Synthesis of Pyrrolidine-Fused [34]- and [36]Octaphyrins via 1,3-Dipolar Cycloaddition
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https://figshare.com/articles/dataset/Synthesis_of_Pyrrolidine_Fused_34_and_36_Octaphyrins_via_1_3_Dipolar_Cycloaddition/3233089
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资源简介：
The utility of expanded porphyrins as a dipolarophile in cycloaddition reactions has been investigated. The 1,3-dipolar cycloaddition of meso-octakis(pentafluorophenyl)[36]octaphyrin(1.1.1.1.1.1.1.1) with an azomethine ylide provides mono- and bis-pyrrolidine-fused octaphyrins regio-
and stereoselectively. Treatment of the cycloadduct with MnO2 afforded [34]octaphyrin quantitatively.
创建时间：
2006-03-16
