Synthesis, Characterization, and Reactivities of Molybdenum and Tungsten PONOP Pincer Complexes
收藏NIAID Data Ecosystem2026-03-09 收录
下载链接：
https://figshare.com/articles/dataset/Synthesis_Characterization_and_Reactivities_of_Molybdenum_and_Tungsten_PONOP_Pincer_Complexes/3798498
下载链接
链接失效反馈官方服务：
资源简介：
A new series of molybdenum
and tungsten tricarbonyl pincer complexes,
bearing pyridine-based PONOP-type pincer ligands, have been synthesized
and fully characterized. Addition of HBF4·Et2O to these tricarbonyl complexes generated seven-coordinate molybdenum
and tungsten hydride complexes, and these compounds have been isolated
in good yields. These metal hydrides show fluxional behavior in solution.
The hydride ligands on these metal complexes are acidic in nature
and are readily deprotonated by bases. The molybdenum hydride complex
is shown to catalyze isomerization of 1-hexene to internal isomers
under mild conditions.
创建时间：
2016-09-20
