Gold(I)-Catalyzed Dearomative Rautenstrauch Rearrangement: Enantioselective Access to Cyclopenta[<i>b</i>]indoles

NIAID Data Ecosystem2026-03-08 收录

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https://figshare.com/articles/dataset/Gold_I_Catalyzed_Dearomative_Rautenstrauch_Rearrangement_Enantioselective_Access_to_Cyclopenta_i_b_i_indoles/2187415

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资源简介：

A highly enantioselective dearomative Rautenstrauch rearrangement catalyzed by cationic (S)-DTBM-Segphosgold(I) is reported. This reaction provides a straightforward method to prepare enantioenriched cyclopenta[b]indoles. These studies show vast difference in enantioselectivity in the reactions of propargyl acetates and propargyl acetals in the chiral ligand-controlled Rautenstrauch reaction.

创建时间：

2016-02-14