Symmetrization in a Phosphinidene-Bridged Complex To Give a Diphosphanediyl Derivative with Metal-Centered Reactivity
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https://figshare.com/articles/dataset/Symmetrization_in_a_Phosphinidene_Bridged_Complex_To_Give_a_Diphosphanediyl_Derivative_with_Metal_Centered_Reactivity/2567311
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The phosphinidene complex [Mo2Cp(μ-κ1:κ1,η5-PC5H4)(CO)2(η6-HMes*)] reacts with CO to give the diphosphanediyl derivative [Mo2{μ-κ1,η5:κ1,η5-(C5H4)PP(C5H4)}(η6-HMes*)2]. The latter compound features unreactive lone electron pairs at phosphorus, which instead contribute to the electronic communication between metal centers via a weak π(PP)-bonding interaction. As a result, this complex displays metal-centered acid–base and redox behavior.
创建时间：
2016-02-22
