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Divergent Construction of Nitrogen-Containing Polycyclic Compounds with a Dearomatization Strategy

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NIAID Data Ecosystem2026-03-07 收录
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https://figshare.com/articles/dataset/Divergent_Construction_of_Nitrogen_Containing_Polycyclic_Compounds_with_a_Dearomatization_Strategy/2503492
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The oxidative dearomatization of para-substituted o-alkynylanilines afforded 2-alkynyl cyclohexadienimines, which can act as active substrates for reaction with electron-rich styrenes. The reaction is metal-controlled. Bi(OTf)3-catalyzed reactions afforded 3,4-dihydro-cyclopenta[c,d]indoles, and AgOTf-catalyzed reactions provided tricyclic pyrrole derivatives.
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2012-07-20
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