Experimental and Theoretical Study of Gold(III)-Catalyzed Hydration of Alkynes
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https://figshare.com/articles/dataset/Experimental_and_Theoretical_Study_of_Gold_III_Catalyzed_Hydration_of_Alkynes/2270572
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资源简介：
The properties of different Au(III)
halo dithiocarbamate complexes
of structure [AuX2(S2CN(R)2)] as
suitable catalysts for the hydration reaction of phenylacetylene have
been tested. Moderate catalytic activity was found for X = Cl, Br,
while those compounds in which X = I, C6F5 are
inert. A working mechanism involving the initial dissociation of a
labile ligand (Cl or Br) followed by coordination and activation of
the alkyne, solvent-assisted attack of water, and enol tautomerization
has been proposed through computational studies.
创建时间：
2014-07-28
