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Synthesis and Optical Resolution of 9,9‘-Spirobifluorene-1,1‘-diol

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https://figshare.com/articles/dataset/Synthesis_and_Optical_Resolution_of_9_9_Spirobifluorene_1_1_diol/3333055
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资源简介:
9,9‘-Spirobifluorene-1,1‘-diol (SBIFOL) was conveniently synthesized from 1,2-dibromobenzene and 3-bromoanisole in high yield. Both enantiomers of SBIFOL were obtained in 99% ee by inclusion resolution with 2,3-dimethoxy-N,N,N‘,N‘-tetracyclohexylsuccinamide. The absolute configurations were determined by X-ray analysis of a single crystal of molecular complex.
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2016-05-06
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