Comment on “Topological Analysis of the Electron Density in the Carbonyl Complexes M(CO)8 (M = Ca, Sr, Ba)”
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We question the statement of a recent publication (Organometallics 2020, 39, 132, DOI: 10.1021/acs.organomet.9b00699) that the M → CO π backdonation in the alkaline earth carbonyl complexes M(CO)8 (M = Ca, Sr, Ba) is negligible and that the decrease of the CO stretching frequency is rather caused by interligand interactions of the carbonyl groups within the molecules.
创建时间：
2020-08-24
