Synthesis of the A–D Ring System of the Gambieric Acids
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https://figshare.com/articles/dataset/Synthesis_of_the_A_D_Ring_System_of_the_Gambieric_Acids/2126311
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资源简介:
The A–D fragment of gambieric
acids A and C has been synthesized
using an asymmetric Tsuji–Trost allylation reaction to couple
the two key segments. The A ring fragment has been prepared by a short
and highly efficient route involving diastereoselective Lewis acid
mediated alkylation of an acetal. Iterative ring-closing metathesis
reactions have been used to construct cyclic ethers and assemble the
tricyclic B–D fragment.
创建时间:
2016-02-13



