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Synthesis of Oxacalixarenes Incorporating Nitrogen Heterocycles: Evidence for Thermodynamic Control

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NIAID Data Ecosystem2026-03-06 收录
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https://figshare.com/articles/dataset/Synthesis_of_Oxacalixarenes_Incorporating_Nitrogen_Heterocycles_Evidence_for_Thermodynamic_Control/3074836
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Oxacalix[2]arene[2]hetarenes are formed in a single step by cyclooligomerization of meta-diphenols with meta-dichlorinated azaheterocycles. The high selectivity for cyclic tetramer formation results from thermodynamic product control. Macrocycles as large as oxacalix[5]arene[5]hetarenes have been isolated under nonequilibrating conditions.
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2016-03-01
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