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Ligand Design in Rh(diene)-Mediated “Carbene” Polymerization; Efficient Synthesis of High-Mass, Highly Stereoregular, and Fully Functionalized Carbon-Chain Polymers

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NIAID Data Ecosystem2026-03-06 收录
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Stereoselective polymerization of “carbenes” from diazo esters mediated by [(L-prolinate)RhI(Me2cod)] allows the formation of highly syndiotactic, fully functionalized carbon-chain polymers with the highest reported molecular weights in high yields, thus providing the best currently available catalyst for this new reaction.

创建时间:
2016-02-24
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