Novel Diphenoxo-Bridged Dinuclear Zinc Complexes: Generation of Phenoxyl-Radical Species and Nuclease Activity
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https://figshare.com/articles/dataset/Novel_Diphenoxo_Bridged_Dinuclear_Zinc_Complexes_Generation_of_Phenoxyl_Radical_Species_and_Nuclease_Activity/2734327
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资源简介：
Tridentate ligand PhimpH having N2O donors binds to zinc(II) after deprotonation, affording novel diphenoxo-bridged dinuclear zinc complexes [Zn2(Phimp)2(ClO4)2] (1) and [Zn2(Phimp)2(Cl)2]·CH2Cl2 (2·CH2Cl2). The molecular structure of 2·CH2Cl2 revealed some unique structural features. The phenoxyl-radical complexes were generated at room temperature, and these radical complexes exhibited nuclease activity with pBR322 DNA.
创建时间：
2010-09-06
