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AgSCF3‑Mediated Oxidative Trifluoromethythiolation of Alkynes with Dearomatization to Synthesize SCF3‑Substituted Spiro[4,5]trienones

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Figshare2016-07-11 更新2026-04-29 收录
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https://figshare.com/articles/dataset/AgSCF_sub_3_sub_Mediated_Oxidative_Trifluoromethythiolation_of_Alkynes_with_Dearomatization_to_Synthesize_SCF_sub_3_sub_Substituted_Spiro_4_5_trienones/3466958
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A new method for the AgSCF3-mediated radical cascade difunctionalizing trifluoromethythiolation of alkynes with dearomatization is developed. This protocol provides a novel route to SCF3-substituted spirocyclic compounds via the formation of one C–SCF3 bond, one C–C bond, and one C–O double bond in a single step.
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2016-07-11
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