Catalytic Asymmetric Addition of Thiols to Nitrosoalkenes Leading to Chiral Non-Racemic α-Sulfenyl Ketones
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https://figshare.com/articles/dataset/Catalytic_Asymmetric_Addition_of_Thiols_to_Nitrosoalkenes_Leading_to_Chiral_Non_Racemic_Sulfenyl_Ketones/2625572
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资源简介：
The first asymmetric organocatalytic sulfenylation of in situ derived nitrosoalkenes leading to chiral nonracemic α-sulfenylated ketones is described. The transformation proceeds in an umpolung fashion, relative to enolate/azaenolate methods, and uses simple thiols, thereby obviating the need for electrophilic sulfur reagents.
创建时间：
2016-02-23
