Silver-Catalyzed Long-Distance Aryl Migration from Carbon Center to Nitrogen Center
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https://figshare.com/articles/dataset/Silver_Catalyzed_Long_Distance_Aryl_Migration_from_Carbon_Center_to_Nitrogen_Center/2105044
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Selective cleavage of an inert C–C bond followed by C–O/N bond formation through a long-distance aryl migration from a carbon to a nitrogen center via Ag catalysis is reported. The migration products were easily converted into γ-hydroxy amines and tetrahydroquinoline derivatives in quantitative yields. Preliminary mechanistic studies indicated a radical pathway.
创建时间：
2016-02-12
