Spin Crossover in Anionic Cobalt-Bridged Fullerene (Bu4N+){Co(Ph3P)}2(μ2‑Cl–)(μ2‑η2,η2‑C60)2 Dimers
收藏Figshare2016-12-19 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Spin_Crossover_in_Anionic_Cobalt-Bridged_Fullerene_Bu_sub_4_sub_N_sup_sup_Co_Ph_sub_3_sub_P_sub_2_sub_sub_2_sub_Cl_sup_sup_sub_2_sub_sup_2_sup_sup_2_sup_C_sub_60_sub_sub_2_sub_Dimers/4482674
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资源简介：
A spin crossover phenomena is observed in an anionic (Bu4N+){Co(Ph3P)}2(μ2-Cl–)(μ2-η2,η2-C60)2·2C6H14 (1) complex in which two cobalt atoms bridge two fullerene molecules to form a dimer. The dimer has a triplet ground state with two weakly coupling Co0 atoms (S = 1/2). The spin transition realized above 150 K is accompanied by a cobalt-to-fullerene charge transfer that forms a quintet excited state with a high spin CoI (S = 1) and C60•– (S = 1/2).
创建时间：
2016-12-19
