Rhodium-Catalyzed Vinylcyclopropanation/Cyclopentenation of Strained Alkenes via a Sequential Carborhodation Process
收藏NIAID Data Ecosystem2026-03-06 收录
下载链接：
https://figshare.com/articles/dataset/Rhodium_Catalyzed_Vinylcyclopropanation_Cyclopentenation_of_Strained_Alkenes_via_a_Sequential_Carborhodation_Process/2870122
下载链接
链接失效反馈官方服务：
资源简介：
A rhodium-catalyzed reaction of dienylboronate esters with alkenes is described. Strained bicyclic alkenes show the highest reactivity toward the rhodium-catalyzed addition of the dienylboronate esters. Depending on the substitution pattern of dienylboronate esters, an intramolecular 1,6- or 1,4-addition mechanism may be operative, affording carbocycles containing a vinylcyclopropane or cyclopentene moiety.
创建时间：
2009-03-20
