A Transition Metal Lewis Acid/Base Triad System for Cooperative Substrate Binding
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https://figshare.com/articles/dataset/A_Transition_Metal_Lewis_Acid_Base_Triad_System_for_Cooperative_Substrate_Binding/2437294
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资源简介：
A frustrated
Lewis pair accessory functionality is positioned in
the secondary coordination sphere of a terpyridine ligand (TpyBN = 6-morpholino-2,2′:6′,2″-terpyridine-6″-boronic
acid pinacol ester) to promote directed Lewis acid/base interactions.
Following metalation with VCl3, the utility of the metal
Lewis acid/base triad (LABT) is highlighted with N2H4 as a cooperatively coordinated substrate, affording the first
η2-[N2H3]− vanadium complex.
创建时间：
2016-02-19
