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Synthesis of New Tren-Based Tris-Macrocycles. Anion Cluster Assembling Inside the Cavity Generated by a Bowl-Shaped Receptor

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NIAID Data Ecosystem2026-03-06 收录
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https://figshare.com/articles/dataset/Synthesis_of_New_Tren-Based_Tris-Macrocycles_Anion_Cluster_Assembling_Inside_the_Cavity_Generated_by_a_Bowl-Shaped_Receptor/3693972
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资源简介:
The synthesis of three new tris-macrocycles, containing three [12]aneN4 (L1), [12]aneN3O (L2), or [14]aneN4 (L3) moieties appended to a tren unit, is reported. The crystal structure of the [(Na(ClO4)6)⊂L12H13]Na6Cl2(ClO4)12 compound shows the anionic cluster [Na(ClO4)6]5- assembled inside the cavity defined by two bowl-shaped polyammonium receptors, held by multiple charge−charge and hydrogen bond interactions.
创建时间:
2016-08-19
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