碳-氧键定向氧化制酮酸类化学品的纳米催化新技术

以生物质资源替代化石资源制备燃料及精细化学品受到广泛关注，符合以生态环境为核心的可持续发展战略和国家重大需求。生物质资源分子富含氧和碳氧键，化学键类型丰富，化学键定点活化难度大。因此，核心科学问题是碳-氧键的定点活化和定向转化/重组。本课题聚焦生物质能源产业的可持续发展，瞄准碳-氧键定向转化纳米催化共性技术，以甘油、乙醇等生物质小分子向高附加值醇/酮/酸转化为目标反应，开展了从应用基础、技术开发到工程化的全链条研究，旨在推进生物质资源高值化利用的产业化进程。Replacing fossil resources with biomass resources to produce fuels and fine chemicals has garnered widespread attention, as it aligns with the eco-environment-centric sustainable development strategy and major national strategic demands. Biomass-derived molecules are rich in oxygen and C-O bonds, with diverse types of chemical bonds, posing great challenges to the site-selective activation of these bonds. Hence, the core scientific issue is the site-selective activation and targeted transformation/reorganization of C-O bonds. This research project focuses on the sustainable development of the biomass energy industry, targets the universal nanocatalysis technology for targeted C-O bond transformation, takes the conversion of small biomass molecules such as glycerol and ethanol into high-value-added alcohols, ketones and acids as the target reaction, and has carried out full-chain research spanning applied basic research, technology development and engineering scale-up, aiming to promote the industrialization process of high-value utilization of biomass resources.

搜集汇总

背景与挑战

背景概述

该数据集围绕生物质资源中碳-氧键的定向氧化转化技术，专注于纳米催化方法，以甘油、乙醇等小分子为原料制备高附加值酮酸类化学品。数据集包含从基础研究到工程化的全链条数据，旨在推动生物质高值化利用的产业化进程，数据量43.75MB，共73个文件，源于国家重点研发计划项目。