Formation of Superoxide Anion on Aerial Oxidation of Cu(II)–Porphyrinogen in the Synthesis of Tetrakis(cyclohexyl)porphyrinogenCu(III) Anion
收藏NIAID Data Ecosystem2026-03-06 收录
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https://figshare.com/articles/dataset/Formation_of_Superoxide_Anion_on_Aerial_Oxidation_of_Cu_II_Porphyrinogen_in_the_Synthesis_of_Tetrakis_cyclohexyl_porphyrinogenCu_III_Anion/2933626
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资源简介：
Tetraethylammonium–tetrakis(cyclohexyl)porphyrinogenCu(II) (1) is spontaneously oxidized by aerial oxygen to the corresponding Cu(III) (2) species, producing 1 equiv of O2−. Steric crowding of the peripheral hydrogens in 1 prevented any direct Cu−O2 bond formation in the oxidation process, which suggests an outer-sphere electron transfer reaction.
创建时间：
2016-02-27
