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Data from: Genuine Carbene Versus Carbene-Like Reactivity

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DataCite Commons2024-09-06 更新2025-04-16 收录
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Abstract: Singlet carbenes are not always isolable and often even elude direct detection. When they escape observation, their formation can sometimes be evidenced by in situ trapping experiments. However, is carbene-like reactivity genuine evidence of carbene formation? Herein, using the first example of a spectroscopically characterized cyclic (amino)(aryl)carbene (CAArC), we cast doubt on the most common carbene trapping reactions as sufficient proof of carbene formation.
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UC San Diego Library Digital Collections
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2024-09-06
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