Oxidative Addition of Secondary C–X Bonds to Palladium(0): A Beneficial Anomeric Acceleration
收藏Figshare2016-02-23 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Oxidative_Addition_of_Secondary_C_X_Bonds_to_Palladium_0_A_Beneficial_Anomeric_Acceleration/2649688
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资源简介：
The oxidative addition of secondary electrophiles to Pd(0) is significantly accelerated by anomeric effects. In contrast to cyclohexyl bromide, acetobromo-α-d-glucose undergoes invertive oxidative addition to tris(triethylphosphine)palladium(0) to generate a stable, isolable organometallic complex, Pd(PEt3)2(Br)(AcO-β-glucose), which has been fully characterized but is prone to β-acetoxy elimination.
创建时间：
2016-02-23
