A Versatile, Traceless C–H Activation-Based Approach for the Synthesis of Heterocycles
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https://figshare.com/articles/dataset/A_Versatile_Traceless_C_H_Activation_Based_Approach_for_the_Synthesis_of_Heterocycles/3207523
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资源简介：
A versatile,
traceless C–H activation-based approach for
the synthesis of diversified heterocycles is reported. Rh(III)-catalyzed, N-amino-directed C–H alkenylation generates either
olefination products or indoles (in situ annulation) in an atom- and
step-economic manner at room temperature. The remarkable reactivity
endowed by this directing group enables scale-up of the reaction to
a 10 g scale at a very low catalyst loading (0.01 mol %/0.1 mol %).
Ex situ annulation of olefination product provides entry into an array
of heterocycles.
创建时间：
2016-05-16
