Synthesis and Structure of a Carbene-Stabilized Boraallene Coordinated to Rhodium
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https://figshare.com/articles/dataset/Synthesis_and_Structure_of_a_Carbene_Stabilized_Boraallene_Coordinated_to_Rhodium/2413549
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资源简介：
Reaction of the (B,C-η2)-1-aza-2-borabutatriene rhodium complex 1 with
1,3-dimethylimidazol-2-ylidene) (IMe, 2) afforded the N-heterocyclic carbene-stabilized (C,C-η2)-1-boraallene rhodium complex 3, which has been
characterized in solution and by X-ray crystallography. Density functional
theory calculations were carried out to elucidate the observed base-induced
B–C to C–C coordination mode shift, which suggested
that the latter is 25 kJ/mol lower in energy.
创建时间：
2016-02-19
