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Synthesis of Amides and Nitriles from Vinyl Azides and p‑Quinone Methides

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Figshare2017-03-24 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Synthesis_of_Amides_and_Nitriles_from_Vinyl_Azides_and_i_p_i_Quinone_Methides/4786063
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A divergent synthesis of amides and nitriles from vinyl azides and p-quinone methides (p-QMs) was developed. The p-QMs could be activated by BF3-Et2O and then nucleophilically attacked by vinyl azides, leading to divergent rearrangement toward amides and nitriles.
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2017-03-24
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