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Fine-Tuning the Single-Molecule Magnet Properties of a [Dy(III)-Radical]2 Pair

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Figshare2016-02-19 更新2026-04-29 收录
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A supramolecular species composed of a pair of nonequivalent Dy­(III)–radical complexes exhibits single-molecule magnet (SMM) properties. The weak effective antiferromagnetic coupling between the Dy­(III) ions can be compensated by application of a small (700 Oe) dc field, revealing the relaxation mode of the two distinct SMMs. These unique results illustrate how the dynamics of a supramolecular [Dy-Radical]2 SMM can be fine-tuned by the exchange-bias and an applied magnetic field.

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2016-02-19
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