Synthetic Studies toward the C14–C29 Fragment of Mirabalin
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https://figshare.com/articles/dataset/Synthetic_Studies_toward_the_C14_C29_Fragment_of_Mirabalin/3810663
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A convergent synthesis of one isomer of the C14–C29 fragment of mirabalin is disclosed. The key steps include a Marshall allenylation, a Mukaiyama aldol reaction and a Crimmins aldolization, which allow the control of 10 out of 25 stereogenic centers present in the molecule.
创建时间:
2016-09-12



