Base-Stabilized Nitrilium Ions as Convenient Imine Synthons
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下载链接:
https://figshare.com/articles/dataset/Base_Stabilized_Nitrilium_Ions_as_Convenient_Imine_Synthons/2184397
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资源简介:
A simple
and efficient methodology is presented for the synthesis
of a wide range of substituted imines. It is based on stabilizing
readily available, but thermally labile, N-alkylnitrilium
triflates with pyridine or DMAP to moderately air-stable adducts.
These base-stabilized imine synthons react conveniently with phosphorus-
and nitrogen-based nucleophiles to amidines and phosphaamidines.
创建时间:
2016-02-14



