Bistable and Porous Metal–Organic Frameworks with Charge-Neutral <b>acs</b> Net Based on Heterometallic M<sub>3</sub>O(CO<sub>2</sub>)<sub>6</sub> Building Blocks
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A Co(II)–Ti(IV) heterometallic approach is successfully adopted to synthesize charge-neutral metal–organic frameworks based on oxo-centered trinuclear cluster and linear dicarboxylate linkers. Unlike their homonuclear predecessors, the cobalt–titanium–organic frameworks not only display a permanent porosity but also show an irreversible phase transition between two stable forms as unambiguously characterized by single-crystal and powder X-ray diffraction studies.
创建时间：
2016-02-18
