Chiral Phosphaalkene−Oxazoline Ligands for the Palladium-Catalyzed Asymmetric Allylic Alkylation
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资源简介：
Enantioselective catalysis in moderate to excellent yields and ee’s has been accomplished using a phosphaalkene-based ligand system. Specifically, the palladium-catalyzed allylic alkylation of 1,3-diphenyl-2-propenyl acetate using a chiral P(sp2),N(sp2) ligand proceeds with a variety of malonate nucleophiles in 73−95% yield (79−92% ee).
创建时间：
2010-10-15
