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Selective Si−C Bond Cleavage as Synthetic Entry to a Functionalized Lithiosilane

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https://figshare.com/articles/dataset/Selective_Si_C_Bond_Cleavage_as_Synthetic_Entry_to_a_Functionalized_Lithiosilane/3283033
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资源简介:
Treatment of the phenyl-substituted silane 4 with lithium metal afforded the functionalized lithiosilane rac-2 by selective cleavage of one Si−C bond between silicon and a phenyl group. The resulting lithiosilane rac-2 crystallizes as the dimer (2·THF)2, which represents the first example of a dimeric organyl-substituted lithiosilane in the presence of THF.
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2005-06-08
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