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Ruthenium(II) Catalyzed Regiospecific C–H/O–H Annulations of Directing Arenes via Weak Coordination

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NIAID Data Ecosystem2026-03-09 收录
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https://figshare.com/articles/dataset/Ruthenium_II_Catalyzed_Regiospecific_C_H_O_H_Annulations_of_Directing_Arenes_via_Weak_Coordination/2107036
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资源简介:
Ruthenium­(II) catalyzed oxidative C–H/O–H annulations have been demonstrated using two different directing arenes viz. 2-arylquinolinone and 2-arylbenzoxazinone with internal alkynes. Regiospecific annulations have been observed for both directing arenes via the assistance of weaker carbonyl oxygen in the presence of a stronger nitrogen-directing site. In this substrate-controlled convergent protocol the weaker directing group dictates the annulation path.
创建时间:
2016-02-12
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