Catalytic Reductive Coupling of 9-Bromofluorene
收藏NIAID Data Ecosystem2026-03-06 收录
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The reductive homocoupling of 9-bromofluorene is catalyzed by 0.1 mol % Ru3(CO)12 in refluxing xylene, with a TON in excess of 3000. A stoichiometric reaction affords the novel cluster Ru4(μ3-OMe)(μ3-OH)(μ-Br)2(CO)10, which is found to be even more catalytically active. Further reaction of this cluster with bromofluorene gives another novel cluster, Ru4(μ4-O)(μ-Br)6(CO)8, which is inactive.
创建时间：
2016-05-05
