Asymmetric Intramolecular Cyclobutane Formation via Photochemical Reaction of <i>N,N</i>-Diallyl-2-quinolone-3-carboxamide Using a Chiral Crystalline Environment
收藏NIAID Data Ecosystem2026-03-07 收录
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Crystal structures and photochemical reactions of three N,N-diallyl-2-quinolone-3-carboxamides were investigated. One quinolonecarboxamide afforded chiral crystals of a P21 crystal system by spontaneous crystallization, and the molecular chirality in the crystal was effectively transferred to cyclobutane in 96% ee by an intramolecular 2 + 2 photocycloaddition reaction in the solid state.
创建时间：
2016-02-22
