Synthesis of a Dinuclear Ferrocene-Linked Bis(phosphinoamide)scandium Hydride Complex
收藏Figshare2016-02-18 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Synthesis_of_a_Dinuclear_Ferrocene_Linked_Bis_phosphinoamide_scandium_Hydride_Complex/2362507
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The ferrocene-based bis(phosphinoamide) fc(NHPiPr2)2 (where fc = 1,1′-ferrocenyl) has been synthesized and coordinated to scandium via alkane elimination. The subsequent reaction of fc(NPiPr2)2ScCH2SiMe3(THF) with H2 yields a dinuclear scandium hydride species wherein the scandium centers are bridged by both hydride and phosphinoamide fragments.
创建时间:
2016-02-18



