A New Dimension in Cyclic Coinage Metal Pyrazolates: Decoration with a Second Ring of Coinage Metals Supported by Inter-ring Metallophilic Interactions
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https://figshare.com/articles/dataset/A_New_Dimension_in_Cyclic_Coinage_Metal_Pyrazolates_Decoration_with_a_Second_Ring_of_Coinage_Metals_Supported_by_Inter_ring_Metallophilic_Interactions/2550118
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资源简介:
When pyrazolate ligands with thioether chelate arms are
used in
cyclic coinage metal pyrazolates [Au(μ-pz)]n, the inner gold ring can be framed with an outer silver ring
to give novel heterometallic double-crowned complexes [AuAg(μ-Lx)(BF4)]4. They feature short intramolecular
in-plane Ag–Au interactions, are stable as octanuclear species
in solution, and show promising luminescence properties.
创建时间:
2012-02-15



