A New Dimension in Cyclic Coinage Metal Pyrazolates: Decoration with a Second Ring of Coinage Metals Supported by Inter-ring Metallophilic Interactions
收藏NIAID Data Ecosystem2026-03-07 收录
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When pyrazolate ligands with thioether chelate arms are used in cyclic coinage metal pyrazolates [Au(μ-pz)]n, the inner gold ring can be framed with an outer silver ring to give novel heterometallic double-crowned complexes [AuAg(μ-Lx)(BF4)]4. They feature short intramolecular in-plane Ag–Au interactions, are stable as octanuclear species in solution, and show promising luminescence properties.
创建时间：
2012-02-15
