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Stepwise Construction of Discrete Heterometallic Coordination Cages Based on Self-Sorting Strategy

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https://figshare.com/articles/dataset/Stepwise_Construction_of_Discrete_Heterometallic_Coordination_Cages_Based_on_Self_Sorting_Strategy/2320057
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A chelation-directed self-sorting synthesis of a series of cationic heterometallic coordination cages (HCCs) with tunable sizes is described. Two complexation modes were found in the cage-forming process. Metal-anchoring host–guest behavior and size-selective in-cage catalytic activities were found for the HCCs.
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2014-02-26
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