Asymmetric Synthesis of CF3- and Indole-Containing Thiochromanes via a Squaramide-Catalyzed Michael–Aldol Reaction
收藏Figshare2016-08-01 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Asymmetric_Synthesis_of_CF_sub_3_sub_-_and_Indole-Containing_Thiochromanes_via_a_Squaramide-Catalyzed_Michael_Aldol_Reaction/3474743
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A Michael–aldol reaction of 2-mercaptobenzaldehyde with β-indole-β-CF3 enones catalyzed by a squaramide has been realized. The method affords a series of 2-CF3-2-indole-substituted thiochromanes featuring a CF3-containing quaternary stereocenter in excellent yields, diastereoselectivities, and enantioselectivities.
创建时间：
2016-08-01
