Synthesis and Structural Study of Thiacyclophanes Utilizing Dibromides and Methane Dithiolate
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The synthesis of a series of thiacyclophanes and optically active binaphthol-based chiral thiacyclophanes is reported with XRD structure. Two diastereomeric tetrathiacyclophanes are designed and synthesized. The two diastereomers are evidenced by crystal structure; the single- crystal X-ray studies reveal that one of the isomers possesses an inherent property of self-assembling into a vertical stack of tunnel-like structures.
创建时间：
2016-05-06
