A Percyanovinylidene−Ruthenium Complex, Ru{CC5(CN)3[C(CN)2]2}(dppe)Cp*

Figshare2016-02-23 更新2026-04-29 收录

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https://figshare.com/articles/dataset/A_Percyanovinylidene_Ruthenium_Complex_Ru_C_C_sub_5_sub_CN_sub_3_sub_C_CN_sub_2_sub_sub_2_sub_dppe_Cp_/2692408

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The reaction between Ru(CCCCAg)(dppe)Cp* and tcne affords a novel percyanovinylidene complex by an unusual decyano-dimerization reaction of the cyanocarbon with the diynyl fragment. This complex is also obtained from tcne and Ru{CCCC[Au(PPh3)]}(dppe)Cp*, together with Ru{CCC[C(CN)2]C[Au(PPh3)]C(CN)2}(dppe)Cp*, formed by the anticipated [2 + 2] cycloaddition and subsequent ring-opening reactions.

创建时间：

2016-02-23