Catalytic Hydroamination of Unactivated Olefins Using a Co Catalyst for Complex Molecule Synthesis
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https://figshare.com/articles/dataset/Catalytic_Hydroamination_of_Unactivated_Olefins_Using_a_Co_Catalyst_for_Complex_Molecule_Synthesis/2250916
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资源简介：
Functional
group tolerance is one of the important requirements
for chemical reactions, especially for the synthesis of complex molecules.
Herein, we report a mild, general, and functional group tolerant intramolecular
hydroamination of unactivated olefins using a Co(salen) complex, an N-fluoropyridinium salt, and a disiloxane reagent. This
method, which was carried out at room temperature (or 0 °C),
afforded three-, five-, six-, and seven-membered ring nitrogen-containing
heterocyclic compounds and was compatible with diverse functional
groups.
创建时间：
2014-10-01
