Novel Synthesis of Acyloxyferrole Complexes from Alkynes and Their Conversion to Cyclobutenediones
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https://figshare.com/articles/dataset/Novel_Synthesis_of_Acyloxyferrole_Complexes_from_Alkynes_and_Their_Conversion_to_Cyclobutenediones/3351541
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资源简介:
Acyloxyferrole complexes are easily prepared
by the reaction of alkynes and Fe3(CO)12/Et3N in THF,
which upon reaction with Br2 in dichloromethane at
−78 °C give the corresponding cyclobutenediones in
60−90% yields. The acyloxyferrole complex prepared
using diphenylacetylene and acetyl chloride was characterized by single-crystal X-ray analysis.
创建时间:
2016-05-07



