Postsynthetic Exchanges of the Pillaring Ligand in Three-Dimensional Metal–Organic Frameworks
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https://figshare.com/articles/dataset/Postsynthetic_Exchanges_of_the_Pillaring_Ligand_in_Three_Dimensional_Metal_Organic_Frameworks/2425576
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资源简介：
Metal–organic frameworks,
[Ni(HBTC)(dabco)] (2) and [Ni2(HBTC)2(bipy)0.6(dabco)1.4] (3) (where
H3BTC is 1,3,5-benzenetricarboxylic
acid, dabco is 1,4-diazabicyclo[2.2.2]octane, and bipy is 4,4′-bipyridine),
were prepared via postsynthetic ligand exchanges of [Ni(HBTC)(bipy)]
(1). By controlling the concentration of dabco, we could
obtain not only entropically favorable 2 with completely
exchanged dabco but also enthalpically favorable 3 with
selectively exchanged bipy/dabco in the alternating layers.
创建时间：
2016-02-19
