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Terminal Titanium(IV) (Trimethylsilyl)imides Prepared by Oxidatively Induced Trimethylsilyl Abstraction

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https://figshare.com/articles/dataset/Terminal_Titanium_IV_Trimethylsilyl_imides_Prepared_by_Oxidatively_Induced_Trimethylsilyl_Abstraction/3221533
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资源简介:
Titanium (trimethylsilyl)imide triflate complexes of the type (L)TiNSiMe3(OTf) (L- = [ArNC(CH3)]2CH, Ar = 2,6-iPr2C6H3; L- = N[2-P(CHMe2)2-4-MeC6H3]2) can be readily prepared by one-electron oxidation and subsequent trimethylsilyl abstraction in the Ti(III) precursors (L)TiCl(N{SiMe3}2).
创建时间:
2006-05-22
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