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An Unexpected Phosphine-Catalyzed [3 + 2] Annulation. Synthesis of Highly Functionalized Cyclopentenes

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https://figshare.com/articles/dataset/An_Unexpected_Phosphine_Catalyzed_3_2_Annulation_Synthesis_of_Highly_Functionalized_Cyclopentenes/2922649
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An unexpected phosphine-catalyzed [3 + 2] annulation from electron-deficient allenes and substituted alkylidenemalononitriles was realized in which the allylic moiety of the substituted alkylidenemalononitriles served as the three carbon unit of the cyclopentenes instead of the electron-deficient allenes.
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2008-08-07
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