Direct Observation of a {Re<sub>6</sub>(μ<sub>3</sub>-S)<sub>8</sub>} Core-to-Ligand Charge-Transfer Excited State in an Octahedral Hexarhenium Complex
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A new complex, [Re6S8Cl5ppy]3– (ppy = 4-phenylpyridine), was synthesized and characterized. The complex showed red emission at 296 K in both the crystalline phase and CH3CN. The transient absorption spectrum of [Re6S8Cl5ppy]3– revealed that the emissive excited state involved the {Re6(μ3-S)8} core-to-ligand charge-transfer character.
创建时间：
2011-10-17
