Unusual Thiolate-Bridged Diiron Clusters Bearing the cis-HNNH Ligand and Their Reactivities with Terminal Alkynes
收藏Figshare2016-02-23 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Unusual_Thiolate_Bridged_Diiron_Clusters_Bearing_the_i_cis_i_HN_NH_Ligand_and_Their_Reactivities_with_Terminal_Alkynes/2693032
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资源简介：
A series of well-defined thiolate-bridged diiron clusters bearing the cis-HNNH ligand, [Cp†Fe(μ-SEt)2(μ-η1:η1-HNNH)FeCp†][PF6] (Cp† = η5-C5Me4H or η5-C5Me5), are successfully prepared in high yields and fully characterized by spectroscopy and X-ray crystallography. Under moderate conditions, these new Fe/S clusters exhibit high activity, not only for the catalytic cleavage of the N−N bond of hydrazines but also for the activation and coupling of terminal alkynes.
创建时间：
2016-02-23
