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Azaboradibenzo[6]helicene: Carrier Inversion Induced by Helical Homochirality

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下载链接:
https://figshare.com/articles/dataset/Azaboradibenzo_6_helicene_Carrier_Inversion_Induced_by_Helical_Homochirality/2464096
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资源简介:
Azaboradibenzo­[6]­helicene, a new semiconductor material possessing helical chirality, has been synthesized via a tandem bora-Friedel–Crafts-type reaction. Unprecedented carrier inversion between the racemate (displaying p-type semiconductivity) and the single enantiomer (displaying n-type semiconductivity) was observed and can be explained by changes in the molecular packing induced by helical homochirality.
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2012-12-05
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