Azaboradibenzo[6]helicene: Carrier Inversion Induced by Helical Homochirality
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https://figshare.com/articles/dataset/Azaboradibenzo_6_helicene_Carrier_Inversion_Induced_by_Helical_Homochirality/2464096
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资源简介:
Azaboradibenzo[6]helicene,
a new semiconductor material possessing
helical chirality, has been synthesized via a tandem bora-Friedel–Crafts-type
reaction. Unprecedented carrier inversion between the racemate (displaying
p-type semiconductivity) and the single enantiomer (displaying n-type
semiconductivity) was observed and can be explained by changes in
the molecular packing induced by helical homochirality.
创建时间:
2012-12-05



